Andy Murray will start the defence of his Wimbledon title against Belgian David Goffin.
Murray and Goffin will open play on Centre Court at 13:00 BST on Monday’s first day of the championships.
Top seed Novak Djokovic faces Andrey Golubev while Rafael Nadal will play Martin Klizan and Roger Federer starts against Paolo Lorenzi.
Women’s top seed Serena Williams will play Anna Tatishvili and second seed Li Na will face Paula Kania.
French Open champion Maria Sharapova opens against British wildcard Samantha Murray while British number one Heather Watson will play Alja Tomljanovic.
Fellow Britons, Tara Moore and Naomi Broady play Vera Zvonareva and Timea Babos respectively.